In the extraciton of Silver and Gold, NaCN is used to leach the metal.
4Au(s)+8CN−(aq)+2H2O+O2(g)→4[Au(CN)2]−(aq)+4OH−(aq)
2[Au(CN)2]−(aq)+Zn→2Au(s)+[(Zn(CN)4)]2−(aq)
During extraction of Zn, NaCN is used as a depressant during the froth floatation of ZnS