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Question

In Lassaigne's test, if both N and S are present in the organic compound, they are converted to:

A
Na2S and NaCN
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B
NaSCN
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C
Na2SO3 and NaCN
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D
Na2S and NaCNO
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Solution

The correct option is C NaSCN
When only N or S are present,

Na+C+NΔNaCN

2Na+SΔNa2S

If both nitrogen and sulphur are present in an organic compound, fusion will convert it into sodium thiocyanate.
Na+C+N+SΔNaSCN

Option B is correct.

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