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Question

In Mac-Arthur Forrest method, silver is extracted from solution of Na[Ag(CN)2] by the use of

A
Fe
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B
Mg
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C
Cu
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D
Zn
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Solution

The correct option is D Zn
Cyanide process is used for extraction of Ag which is also called Mc-Arthur forest process.Reactions occurs in extraction of silver -
Ag2S+4NaCN2Na[Ag(CN)2]+Na2S (reversible reaction)
4Na2S+5O2+H2O2Na2SO4+4NaOH+2S
and 2Na[Ag(CN)2]+ZnNa2[Zn(CN)4]+2Ag

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