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Question

In metal halides in higher oxidation state of the metal is more covalent than the one in lowest oxidation state (PbCl4 is more covalent than PbCl2)

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Solution

The halides in higher oxidation state posses high charge and are smaller in size as compared to the lower oxidation state halides.
Thus, in higher oxidation halides the charge/radius ratio is higher which contribute to the increase in polarisation and consequently these are more covalent.

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