In nitroprusside ion the iron and NO exist as FeII and NO+ rather than FeIII and NO. These forms can be differentiated by :
A
estimating the concentration of iron.
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B
measuring the concentration of CN−.
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C
measuring the solid state magnetic moment.
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D
thermally decomposing the compound
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Solution
The correct option is C measuring the solid state magnetic moment. As we know, μ=√n(n+2) wher n is no. of unpaired electron. Fe(II) have 4 unpaired electron so it magnetic moment will be less than Fe (III)(5 unpaired electron).