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Question

In nitroprusside ion the iron and NO exist as FeII and NO+ rather than FeIII and NO. These forms can be differentiated by :

A
estimating the concentration of iron.
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B
measuring the concentration of CN.
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C
measuring the solid state magnetic moment.
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D
thermally decomposing the compound
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Solution

The correct option is C measuring the solid state magnetic moment.
As we know,
μ=n(n+2) wher n is no. of unpaired electron.
Fe(II) have 4 unpaired electron so it magnetic moment will be less than Fe (III)(5 unpaired electron).
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