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Question

In order to cause coagulation of 100 mL arsenous sulphide sol 11.2 mL of 2 M NaCl solution is used. What will be the flocculation value of NaCl?

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Solution

The minimum amount of an electrolyte required to cause precipitation of one litre of colloidal solution is called coagulation value or focculation value for the sol.

11.2 mL of 2 M NaCl contain = 11.2×2=22.4 mmol
100 mL of sol require 22.4 mmol NaCl So,
millimole of NaCl require for 1 litre solution
=2×11.2×1000100=224 mmol

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