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Question

In order to coagulate 400 ml of Fe(OH)3 sol completely, 60 ml of 0.1 M KCl is required. What will be the coagulation value of KCl?

A
6
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B
10
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C
15
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D
115
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Solution

The correct option is C 15
Coagulation value is the millimoles of an electrolyte that must be added to 1 L of a colloidal solution for complete coagulation.
Given,
For 400 textmL Fe(OH)3, millimoles of KCl required =molarity×volume(mL)=0.1×60=6
Hence,
For 1000 mL Fe(OH)3, millimoles of KCl required
=6400×1000=15
Hence coagulation value of KCl is 15

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