In order to complete the reaction1- Pentyne - - 4- Octane b - cis -4- Octane a and b will be1 NaNH 2 - CH 3 C H 2 Br - H 2 one mole P d or Ni2 NaNH 2 - CH 3 CH 2 CH 2 Br - H 2 two moles P d or Ni3 NaNH 2 - CH 3 CH 2 CH 2 Br - H 2- one - mole P d or Ni4 NaNH 2 - CH 3 CH 2 CH 2 Br - BH 3- H 2 O 2- OH -A- 2B- 3C- 4D- 1

C) CH_3 CH_2 CH_2 C≡ CH CH_3 CH_2 CH_2 C≡ C Na 4 OctyneCH_3 CH_2 CH_2≡ C CH_2 CH_2 CH_3Pd ...

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SN1 Reaction Mechanism

In order to c...

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$I n o r d e r t o c o m p l e t e t h e r e a c t i o n$

$1 - P e n t y n e a \to 4 - O c t a n e b \to c i s - 4 - O c t a n e a a n d b w i l l b e$

$(1) N a N H_{2}; a C H_{3} C H_{2} B r : H_{2} b (o n e m o l e) P d o r N i$

$(2) N a N H_{2}; C H_{3} C H_{2} C H_{2} B r : H_{2} (t w o m o l e s) P d o r N i$

$(3) N a N H_{2}; C H_{3} C H_{2} C H_{2} B r : H_{2}, (o n e - m o l e) P d o r N i$

$(4) N a N H_{2}; C H_{3} C H_{2} C H_{2} B r : B H_{3}, H_{2} O_{2}, O H^{-}$

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I n o r d e r t o c o m p l e t e t h e r e a c t i o n

1 - P e n t y n e a \to 4 - O c t a n e b \to c i s - 4 - O c t a n e a a n d b w i l l b e

(1) N a N H_{2}; a C H_{3} C H_{2} B r : H_{2} b (o n e m o l e) P d o r N i

(2) N a N H_{2}; C H_{3} C H_{2} C H_{2} B r : H_{2} (t w o m o l e s) P d o r N i

(3) N a N H_{2}; C H_{3} C H_{2} C H_{2} B r : H_{2}, (o n e - m o l e) P d o r N i

(4) N a N H_{2}; C H_{3} C H_{2} C H_{2} B r : B H_{3}, H_{2} O_{2}, O H^{-}

N a N H_{2}

C_{2} H_{5} B r

X

N a N H_{2}

X

N a N H_{2}

N a N H_{2}

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