In order to prepare 1- chloro-propane which of the following reactants can be employed?

Propene and HCl in the presence of peroxide

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Propene and

C l_{2}

followed by treatment with aq.KOH

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Propanol-1 and

S O C l_{2}

/pyridine

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Any of the above can be used

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Solution

The correct option is A Propanol-1 and $S O C l_{2}$ /pyridine
Propanol-1 and $S O C l_{2}$ with pyridine as a solvent can be used to prepare 1 - chloro - propane. The by products $S O_{2}$ and $H C l$ are both gaseous so they go off leaving the actual product.

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N a N O_{2}

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