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Molecular Orbitals of Oxygen

In PO43- ion,...

Question

In $P O_{4}^{3 -}$ ion, the effective charge on each oxygen atom and the $P - O$ bond order respectively are:

A

−0.75, 1.25

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B

- 0.75, 1.0

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C

- 0.75, 0.6

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D

- 3, 1.25

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Solution

The correct option is A −0.75, 1.25
Effective charge of oxygen = $\frac{- 3}{4} = - 0.75$
Bond order= $\frac{n o . o f b o n d}{t o t a l n o . o f r e s o n a t i n g s t r u c t u r e} = \frac{5}{4} = 1.25$

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