The correct option is A the p.d. of the wire between the +ve end of battery to jockey becomes equal to the e.m.f. of the experimental cell.
In general, if the arrangement is not balanced, there will be a potential difference across the galvanometer, G. This will only be zero means balance when the p.d. of the wire between the +ve end of battery to jockey becomes equal to the e.m.f. of the experimental cell.