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Question

In presence of HCl, H2S results the precipitation of Group – 2 elements but no Gp – 4 elements during quantitative analysis. It is due to


A

Higher concentration of S2-

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B

Higher concentration of H+

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C

Lower concentration of S2-

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D

Lower concentration of H+

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Solution

The correct option is C

Lower concentration of S2-


In HCl, the dissociation H2S is suppressed. Hence it will have lower concentration of S2 ions, which results in the precipatation of those sulphides having very low solubility product.


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