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Standard XII
Chemistry
Elevation in Boiling Point
In the Celsiu...
Question
In the Celsius scale, the upper fixed point is:
A
Melting point of ice
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B
Boiling point of water
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C
Boiling point of mercury
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D
Mean of melting point and boiling point of water
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Solution
The correct option is
B
Boiling point of water
The upper fixed point in the Celsius scale is
100
0
C
, which is the boiling point of water.
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Answer the following : (a) The triple-point of water is a standard fixed point in modern thermometry. Why ? What is wrong in taking the melting point of ice and the boiling point of water as standard fixed points (as was originally done in the Celsius scale) ? (b) There were two fixed points in the original Celsius scale as mentioned above which were assigned the number 0 °C and 100 °C respectively. On the absolute scale, one of the fixed points is the triple-point of water, which on the Kelvin absolute scale is assigned the number 273.16 K. What is the other fixed point on this (Kelvin) scale ? (c) The absolute temperature (Kelvin scale) T is related to the temperature tc on the Celsius scale by t_c = T – 273.15 Why do we have 273.15 in this relation, and not 273.16 ? (d) What is the temperature of the triple-point of water on an absolute scale whose unit interval size is equal to that of the Fahrenheit scale ?
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