In the compound $C_{6} H_{5} Z$ which of the following has all predominantly ortho and para directing groups?

Z = - N O_{2}, - C l, - O H

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Z = - O M e, - C N, - N H_{2}

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Z = - N H C O C H_{3}, - C l, - C O O H

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Z = - N H C O C H_{3}, - C H_{3}, - B r

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Solution

The correct option is D $Z = - N H C O C H_{3}, - C H_{3}, - B r$
Groups which direct the incoming group to ortho and para positions are called as ortho and para directing groups.
$- N H C O C H_{3}, - C H_{3}, - B r$ are ortho and para directing groups.
The groups which direct the incoming group to meta position are called Meta directing groups.
$- N O_{2}, - C N, - C O O H$ are meta directing.
Hence the correct option is d.

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