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Question

In the compounds shown above, the correct order of acidity is :

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A
I > IV > III > II
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B
II > IV > I > II
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C
II > I > III > IV
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D
IV > III > I > II
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Solution

The correct option is A IV > III > I > II
CH3 is an activating group and hence decreases acidity of phenol.

NO2 is a deactivating group and hence increases acidity of phenol.

Para positions are more effective than meta positions.

Hence, reactivity is IV>III>I>II.

Option D is correct.

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