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Question

In the crystalline state, PCl5 shows which of the following hybridization/s?

A
sp3
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B
sp2
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C
sp3d
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D
sp3d2
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Solution

The correct options are
A sp3
D sp3d2
In crystalline state, PCl5 is present as [PCl4]+[PCl6] in which the cation is sp3 hybridised and anion is sp3d2 hybridised.

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