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Question

In the Down's process of obtaining sodium, CaCl2 is added:

A
To get high yield of sodium
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B
To improve the quality of sodium obtained
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C
To lower the operating temperature
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D
To act as a reducing agent
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Solution

The correct option is C To lower the operating temperature
Melting point of NaCl is 803oC. After adding CaCl2, melting point of mixture comes to 600oC.
reaction:
Mg2++Ca(OH)2Mg(OH)2+CaCl2dil.HCl−−−MgCl2.6H2O
MgCl2.6H2OMgCl2.2H2OdryHCl−−−MgCl2

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