In the electrolytic extraction of aluminium, the substances which are not used to reduce the melting point of alumina are:
Cryolite
Na3AlF6
In the electrolytic extraction of aluminium, cryolite is used for the reduction of melting point and fluorspar is used for increasing the conductivity of the solution.
Inert graphite is the electrode used in the electrometallurgical (reduction) process. Aluminium is extracted from alumina by electricity which is the strongest reducing agent.