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Question

In the electroysis of AgNO3 solution, 0.7 g of Ag is deposited after a certain period of time. Calculate the quantity of electricity required in coulomb. (Molar mass of Ag is 107.9 g mol1).

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Solution

Given: Mass of Ag deposited = 0.7 g
Molar mass of Ag = 107.9 g mol1
Quantity of electricity, Q = ?
The half-cell reaction is
Ag+(aq)+eAg(s)
1 mole of Ag produced = 107.9 g Ag requires 1 mole of electrons.
0.7 g Ag will require,
=Mass of AgMolar mass of Ag
=0.7107.9=6.49×103molofAg
1 mole electron carry 96500C charge.
6.49×103 mol of electrons will carry
Q=96500×6.49×1031
=626 coulombs.

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