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Question

In the equilibrium,2SO2+O22SO3 the partial pressure of SO2,O2 and SO3 are 0.662,0.10 and 0.331 respectively.What should be the partial pressure of oxygen so that the equilibrium concentration of SO2 and SO3 are equal?

A
0.4atm
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B
1atm
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C
0.8atm
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D
0.25atm
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Solution

The correct option is B 0.4atm

The given reaction,

2SO2+O22SO3

Partial pressure,

2SO2=0.662, O2=0.10, 2SO3=0.331

Kp=pSO32pSO22pO2


=[0.331]2[0.662]2[0.10]

=2.5

Now given that equilibrium condition,

pSO3=pSO2

Kp=pSO32pSO22pO2


2.5=1pO2

po2=12.5=0.4

Hence,

The partial pressure of Oxygen=0.4 atm

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