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Question

In the esterification reaction, the correct order of reactivity of alcohols is:

A
CH3OH>CH3CH2OH>(CH3)2CHOH
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B
CH3OH>(CH3)2CHOH>CH3CH2OH
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C
CH3CH2OH>(CH3)2CHOH>CH3OH
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D
(CH3)2CHOH>CH3CH2OH>CH3OH
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Solution

The correct option is B CH3OH>CH3CH2OH>(CH3)2CHOH
In the esterification reaction, the alcohol acts as a nucleophile (RO).
The nucleophilicity order is:
CH3O>CH3CH2O>(CH3)2CHO
As the bulkiness of the nucleophilic group increases the reactivity towards esterification decreases.
Hence Option A represents the correct order.

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