In the esterification reaction, the correct order of reactivity of alcohols is:
A
CH3OH>CH3CH2OH>(CH3)2CHOH
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B
CH3OH>(CH3)2CHOH>CH3CH2OH
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C
CH3CH2OH>(CH3)2CHOH>CH3OH
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D
(CH3)2CHOH>CH3CH2OH>CH3OH
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Solution
The correct option is BCH3OH>CH3CH2OH>(CH3)2CHOH In the esterification reaction, the alcohol acts as a nucleophile (RO−). The nucleophilicity order is: CH3O−>CH3CH2O−>(CH3)2CHO− As the bulkiness of the nucleophilic group increases the reactivity towards esterification decreases. Hence Option A represents the correct order.