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Question

In the extraction of copper from your mine, we are now in the roasting phase. Broadly, what will be the components of the product that you get out of the reverberatory furnace?


A

Cu2O

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B

Cu2S

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C

FeSiO3

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D

FeS (minor) and FeO (major)

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Solution

The correct options are
B

Cu2S


D

FeS (minor) and FeO (major)


In the roasting process

2CuFeS2+O2Cu2S+2FeS+SO22FeS+3O22FeO+2SO22Cu2S+3O22Cu2O+2SO2

But this is a minor side reaction since Fe has greater affinity for oxygen and hence the following happens:

Cu2O+FeSCu2S+FeO

of Cu2S and FeS only FeS is largely oxidized to FeO


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