In the first order reaction 75% of the reactant disappeared in 1.388 hrs. Calculate the rate constant of the reaction :
Rate of disappearance of the reactant A in the reversable and one step reaction A⇌B at two temperatures is given by −d[A]dt=2.0×10−3s−1[A]−5.0×10−4s−1[B](at 27∘C)−d[A]dt=8.0×10−2s−1[A]−4.0×10−3s−1[B](at 127∘C) The enthapy of the reaction in the given temperature range is