In the following reaction- Aldehyde - Alcohol Acetal Aldehyde Alcohol HCHO t-BuOH CH3CHO MeOHThe best combinations are-

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Glycoside Formation

In the follow...

Question

In the following reaction,

$A l d e h y d e + A l c o h o l H C l - - \to A c e t a l$

Aldehyde Alcohol
$H C H O$ $t - B u O H$
$C H_{3} C H O$ $M e O H$

The best combinations are:

H C H O

and

M e O H

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H C H O

and

t - B u O H

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C H_{3} C H O

and

M e O H

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C H_{3} C H O

and

t - B u O H

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Solution

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H C H O

C H_{3} C H O

H_{2} C = C H - C H O N a O H \to H C H O + C H_{3} C H O

H C H O, C H_{3} C H O and C H_{3} C O C H_{3}

H B r - -- \to

a l c K O H - ----- \to

Z n / H_{2} O - ---- \to O_{3} {C H}_{3} C H O + H C H O

Which of the following is most stable, and which one is least ?
$H C H O$ $C H_{3} C H O$
I II

$C H_{3} C O C H_{3}$ $C l_{3} C C H O$
III IV

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