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Question

In the following reaction, Na2S2O3 is converted to Na2S4O6.
2Na2S2O3+I2Na2S4O6 + 2NaI
The equivalent weight of Na2S2O3 for this reaction is:

(The molecular weight of Na2S2O3=M)

A
M
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B
M4
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C
M2
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D
M3
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Solution

The correct option is A M
The molecular weight of Na2S2O3=MNa2S2O3 + 12I212Na2S4O6 + NaIOxidation state of S in Na2S2O3=+2Oxidation state of S in Na2S4O6=+2.5ΔO.S.=2.52=0.5nf=2×0.5=1Where, O.S. is the oxidation stateEquivalent weight=Molecular weightnf =M1=M

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