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Question

In the following reaction sequence , [C] is :

(i) \( NaNO _{2}+ HCl _{2} 0-5 C \) (ii) \( Cu _{2} Cl _{2}+ HCl \) [A \( ] \) [B] \( Na + \) thy ether [C] (Major Protuct)

A
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B
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C
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D
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Solution

The correct option is C
Initially, amines undergoes diazotisation to form diazonium salt followed by sandmeyer's reaction to give chloro compound.
In next step, chlorination occurs by free radical mechanism followed by wurtz reaction to give the desired product.

Hence, option (c) is correct.

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