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Question

In the following sequence of reactions, identify the end product (D).
Na2CO3SO2(A)Na2CO3(B) ElementalS,Δ(C)I2(D)

A
Na2SO4
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B
Na2S4O6
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C
Na2S
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D
Na2S2O3
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Solution

The correct option is B Na2S4O6
The reactions are shown below.
1) Na2CO3+2SO2+H2O2NaHSO3(A)+CO2
2) 2NaHSO3+Na2CO32Na2SO3(B)+H2O+CO2
3) Na2SO3+SΔNa2S2O3(C)
4) 2Na2S2O3(C)+I2Na2S4O6(D)+2NaI
The product D is Na2S4O6.

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