In the following sequence of reactions, identify the end product (D). Na2CO3SO2→(A)Na2CO3→(B)ElementalS,Δ→(C)I2→(D)
A
Na2SO4
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B
Na2S4O6
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C
Na2S
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D
Na2S2O3
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Solution
The correct option is BNa2S4O6 The reactions are shown below. 1) Na2CO3+2SO2+H2O→2NaHSO3(A)+CO2 2) 2NaHSO3+Na2CO3→2Na2SO3(B)+H2O+CO2 3) Na2SO3+S→ΔNa2S2O3(C) 4) 2Na2S2O3(C)+I2→Na2S4O6(D)+2NaI