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Question

In the following sequence of reactions. The compound C formed will be:


CH−C|HNH2−CH3HNO2−−−−→AOxidation−−−−−−→B(i)CH3Mgl−−−−−−−→(ii)H+/H2OC

A
butanol-1
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B
butanol-2
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C
2-methyl propanol-1
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D
1, 1-dimethylethanol
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Solution

The correct option is D 1, 1-dimethylethanol
The end product (C) is 1, 1-dimethylethanol.
Isopropyl amine reacts with nitrous acid to form isopropyl alcohol. On oxidation acetone is obtained which then reacts with methyl magnesium iodide (a grignard reagent) followed by acid hydrolysis to give 1, 1-dimethylethanol..
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