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Question

In the following sequence of reactions, the end product is:


CH3CCHH2SO4/Hg2+−−−−−−−H2O/60oACH3MgCl−−−−−H2OB

A
acetone
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B
tertiary butyl alcohol
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C
secondary propyl alcohol
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D
ethyl alcohol
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Solution

The correct option is D tertiary butyl alcohol
A is acetone which is formed after oxymercuartion-demercuartion reaction on acetylene. The reaction is as follows:

CH3CCHH2SO4/Hg2+−−−−−−−H2O/60oCH3COCH3CH3MgCl−−−−−H2O(CH3)3COH

Hence, a tertiary alcohol is formed.

Option B is correct.

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