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Question

In the following the correct bond order sequence is:

A
O+2>O2>O22>O2
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B
O+2>O2>O2>O22
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C
O22>O+2>O2>O2
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D
O2>O2>O22>O+2
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Solution

The correct option is B O+2>O2>O2>O22
Electronic configuration and bond order of the given species:
O2:σ1s2 σ1s2 σ2s2 σ2s2σ2p2z π2p2x=π2p2y π2p1x=π2p1y
B.O.=2

O+2:σ1s2 σ1s2 σ2s2 σ2s2σ2p2z π2p2x=π2p2y π2p1x
B.O.=2.5

O2:σ1s2 σ1s2 σ2s2 σ2s2σ2p2z π2p2x=π2p2y π2p2x=π2p1y
B.O.=1.5

O22:σ1s2 σ1s2 σ2s2 σ2s2σ2p2z π2p2x=π2p2y π2p2x=π2p2y
B.O.=1.0

Correct bond order sequence is,

O+2>O2>O2>O22




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