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Question

In the formula P=nRTV−be−aRTV. Find the dimensions of a and b where P=pressure,n=numberofmoles,T=temperature,V=volumeandR=universalgasconstant.

A
[a]=M1L5T2mol1,[b]=L3
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B
[a]=M1L3T2mol1,[b]=L3
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C
[a]=M1L5T2mol1,[b]=L2
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D
None of these
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Solution

The correct option is D [a]=M1L5T2mol1,[b]=L3

[b]=[v]=[L3] dimensions of aRTV=[MLT]

[a]=dimensionsofRTV

=[M1L2T2k×mol]×[k]×[L3]=[M1L5T2mol1]


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