In the given figure, AB is the chord and AC = CB.
Since OC is bisecting the chord AB, OC will be perpendicular to AB.
(The line drawn through the center of a circle to bisect a chord is perpendicular to the chord)
Hence, ∠OCA=90∘
Now in ΔOAC,
∠OCA=90∘
∠AOC=60∘
So, ∠CAO=180∘−(60∘+90∘)=30∘