The correct option is D 120°
Since, PT is a tangent to the circle,
∠OPT=90°... (tangent is perpendicular to the radius of a circle)
So,
∠OPT=∠QPT+∠OPQ⇒90°=60°+∠OPQ⇒∠OPQ=30°
Since,
OP=OQ, ∠OPQ=∠OQP=30°
In △OQP,∠QPO+∠OQP+∠POQ=180°⇒30°+30°+∠POQ=180°⇒∠POQ=120°
So, ∠POQ on the major arc =360°−120°=240°
So,
∠PRQ=12central angle
=12×240°
=120°