General Mechanism of Electrophilic Aromatic Substitution
In the given ...
Question
In the given reaction : [X]+Acetic anhydride → Aspirin [X] will be :
A
benzoic acid
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B
o − methoxybenzoic acid
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C
o − hydroxybenzoic acid
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D
p − hydroxybenzoic acid
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Solution
The correct option is D o − hydroxybenzoic acid The hydroxyl group of o - Hydroxybenzoic acid is acetylated with acetic anhydride to obtain 2-acetoxybenzoic acid also known as aspirin.