In the Hofmann bromamide degradation reaction below RCONH2+KOH+Br2⟶ the intermediates involved are
A
RCONHBr
Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses
B
RNCO
Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses
C
RNH2
No worries! We‘ve got your back. Try BYJU‘S free classes today!
D
RCOONH−K+
No worries! We‘ve got your back. Try BYJU‘S free classes today!
Open in App
Solution
The correct options are ARCONHBr BRNCO
When an amide is treated with Bromine in aqueous or ethanolic solution of sodium hydroxide, a primary amine with one
carbon atom less than the original amide is released. This degradation
reaction is called as Hoffmann bromamide reaction. This reaction
involves the migration of an alkyl or aryl group from the carbonyl
carbon atom of the amide to the nitrogen atom.