The correct options are
A manganese dioxide and sodium chloride
D bleaching powder
In the laboratory chlorine gas can be prepared from manganese dioxide and sodium chloride, red lead and bleaching powder.
2NaCl+MnO2+3H2SO4→2NaHSO4+MNSO4+2H2O+Cl2↑
Bleaching powder liberates Cl2 when treated with mineral acid of CO2.
CaOCl2+2HCl→CaCl2+H2O+Cl2↑
CaOCl2+H2SO4→CaSO4+H2O+Cl2↑
CaOCl2+CO2→CaCO3+Cl2↑