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Question

in the laboratory preparation of HClacid from Nacl and conc.hydrochloric acid the residual salt formed at temperature above 200 celsius forms a hard crust and sticks to the glass. give reason.

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Solution

The reaction proceeds as,

H2SO4 + 2 NaCl > 2000C 2 HCl + Na2SO4

Formation of hard crust of Na2SO4 which sticks to glass


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