In the manufacture of sodium hydroxide, by product obtained is:
Cl2
A brine solution is electrolysed using a mercury cathode and a carbon anode. Sodium metal discharged at the cathode combines with mercury to from sodium amalgam. Chlorine gas is evolved at the anode
Cathode : Na++e−Mg−−→ Sodium amalgam
Anode : Cl−→12Cl2+e−