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Question

In the Nernst Equations,
E=E2.303 RTnFlog10Q
Q will be equal to the equilibrium constant KC, then calculate the cell potential E of the cell.

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Solution

Given, E=E02.303RTnFlog10Q
At condition of equilibrium
cell potential of the cell = 0 and Q = KC
so, we have,
0=E02.303RTnFlog10KC

E0=2.303RTnFlog10KC
putting value of E0 in above equation we have
E=2.303RTnFlog10KC2.303RTnFlog10Q

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