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Byju's Answer
Standard XII
Chemistry
EMF
In the Nernst...
Question
In the Nernst Equations,
E
=
E
∘
−
2.303
R
T
n
F
log
10
Q
Q
will be equal to the equilibrium constant
K
C
, then calculate the cell potential
E
of the cell.
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Solution
Given,
E
=
E
0
−
2.303
∗
R
∗
T
n
F
l
o
g
10
Q
At condition of equilibrium
cell potential of the cell = 0 and Q =
K
C
so, we have,
0
=
E
0
−
2.303
∗
R
∗
T
n
F
l
o
g
10
K
C
E
0
=
2.303
∗
R
∗
T
n
F
l
o
g
10
K
C
putting value of
E
0
in above equation we have
E
=
2.303
∗
R
∗
T
n
F
l
o
g
10
K
C
−
2.303
∗
R
∗
T
n
F
l
o
g
10
Q
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0
Similar questions
Q.
Calculate using Nernst equation cell potential of the following electrochemical cell at
298
K
.
Z
n
(
s
)
|
Z
n
2
+
(
e
q
)
(
0.04
M
)
|
|
S
n
2
+
(
e
q
)
|
S
n
(
s
)
(
0.03
M
)
(Given
E
∘
=
−
0.76
V
,
E
∘
=
−
0.14
V
)
.
Q.
Write Nernst equation for Daniel cell at equilibrium condition and derive relationship between
E
o
(
c
e
l
l
)
and equilibrium constant
(
K
c
)
.
Q.
Derive Nernst equation for the cell.
N
i
(
s
)
|
N
i
2
+
(
a
q
.
0.1
M
)
|
|
A
g
+
(
a
q
.
0.1
M
|
A
g
(
s
)
and also find its cell potential. Given:
E
∘
A
g
+
/
A
g
=
0.80
v
o
l
t
and
E
∘
N
i
2
+
/
N
i
=
−
0.25
v
o
l
t
.
Q.
C
r
(
s
)
|
C
r
3
+
|
|
F
e
2
+
|
F
e
(
s
)
In above cell, the value of
n
in the Nernst equation:
i.e.,
E
=
E
∘
−
0.059
n
log
10
Q
will be:
Q.
Nernst equation is :
E
=
E
o
−
R
T
n
F
l
n
Q
. If
Q
=
K
c
, then which one is not correct?
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