In the precipitation of the iron group in qualitative anlaysis, ammonium chloride is added before adding ammonium hydroxide to :
A
Decrease concentration of OH− ions
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B
Prevent interference by phosphate ions
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C
Increase concentration of Cl− ions
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D
Increase concentration of NH+4 ions
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Solution
The correct option is A Decrease concentration of OH− ions Option (A) is correct. In the precipitation of the iron group in qualitative anlaysis, ammonium chloride is added before adding ammonium hydroxide to decrease concentration of OH− ions so that only Fe, Cr, and Al are precipitated as their hydroxides.