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Question

In the preparation of alkynes from vicinal dihalides, the reaction is

A
Elimination reaction
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B
Substitution reaction
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C
Addition reaction
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D
Rearrangement reaction
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Solution

The correct option is A Elimination reaction
Vicinal dihalides on treatment with alcoholic KOH undergo dehydrohalogenation. One molecule of HX is eliminated to form alkenyl halide which on treatment with sodamide gives alkyne.
for example :
1,2-dibromo propane undergoes dehydrohalogenation to give 2-bromoprop-1-ene which on on further tratment with NaNH2 gives prop-1-yne.


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