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Question

In the process of extraction of gold,
1.) Roasted Au ore + CN(aq)+O2[X]+NaOH
2.) [X]+Zn[Y]+Au

A
X=[Au(CN)2],Y=[Zn(CN)4]2
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B
X=[Au(CN)4]2,Y=[Zn(CN)4]2
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C
X=[Au(CN)2],Y=[Zn(CN)6]4
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D
X=[Au(CN)4],Y=[Zn(CN)4]2
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Solution

The correct option is A X=[Au(CN)2],Y=[Zn(CN)4]2
This reaction is an example of the Cyanide process (Mac Arthur Forrest Process) for extraction of metals like gold or silver.

Reaction:

Au+8NaCN+2H2O+O24Na[Au(CN)2]+4NaOH

Gold is obtained by reaction with Zn:

2Na[Au(CN)2]+ZnNa2[Zn(CN)4]+2Au

Therefore, X=[Au(CN)2] and Y=[Zn(CN)4]2

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