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Question

In the process of extraction of gold, Roasted gold ore+CN(aq)+H2OO2[X]+[OH], [X]+Zn[Y]+Au
Identify the complexes [X] and [Y].

A
[Au(CN)2],[Zn(CN)4]2
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B
[Au(CN)4]3,[Zn(CN)4]2
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C
[Au(CN)2]2,[Zn(CN)6]4
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D
[Au(CN)4],[Zn(CN)4]2
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Solution

The correct option is A [Au(CN)2],[Zn(CN)4]2
4Au+8CN+2H2O+O24[Au(CN)2]+4OH
2[Au(CN)2]+Zn2Au+[Zn(CN)4]2
It is Mc-Arthur process. Here
X=[Au(CN)2] & Y=[Zn(CN)4]2

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