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Question

In the reaction,
A(s)+B(g)+Heat2C(s)+2D(g)
equilibrium is established. The pressure of D is increased and found be doubled when equilibrium is restablished. The factor by which B is changed is:

A
2
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B
3
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C
4
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D
3
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Solution

The correct option is C 4
Assume at equilibrium, the pressures of B and D are 1 and 2 atm respectively.
K=(1)(2)2=4
After second equilibrium, the pressure of C is doubled to 4.
K=(PB)(4)2=4
PB=14.
Thus, the pressure of B is reduced by a factor of 4.

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