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Question

In the reaction
H2(g)+I2(g)2HI(g)
the amounts of H2, I2 and HI are 0.2g,9.2525g and 44.8g respectively at equilibrium at a certain temperature. Calculate the equilibrium constant of the reaction.

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Solution

H2(g)+I2(g)2HI(g)
Applying law of mass action
Kc=[HI]2[I2][H2]
Let the total volume be V litre, then
[H2]=0.2g2g/mol×VL=0.1VM;
[I2]=9.2525g254g/mol×VL=0.0364VM
[HI]=44.8g128g/mol×VL=0.35VmolL1.
so, Kc=(0.35V)20.1V×0.0364V=33.65

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