In the reaction H2(g)+I2(g)⇌2HI(g) the amounts of H2, I2 and HI are 0.2g,9.2525g and 44.8g respectively at equilibrium at a certain temperature. Calculate the equilibrium constant of the reaction.
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Solution
H2(g)+I2(g)⇌2HI(g) Applying law of mass action Kc=[HI]2[I2][H2] Let the total volume be V litre, then [H2]=0.2g2g/mol×VL=0.1VM; [I2]=9.2525g254g/mol×VL=0.0364VM [HI]=44.8g128g/mol×VL=0.35VmolL−1. so, Kc=(0.35V)20.1V×0.0364V=33.65