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Question

In the reaction PCl5(g)PCl3(g)+Cl2(g) the equilibrium concentration of PCl5 and PCl3 are 0.4 and 0.2 mole/litre respectively. If the value of KC is 0.5 what is concentration of Cl2 in moles/litre ?

A
2
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B
1.5
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C
1
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D
0.5
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Solution

The correct option is C 1
The equilibrium reaction is PCl5(g)PCl3(g)+Cl2(g).
The value of the equilibrium constant is Kc=[PCl3][Cl2][PCl5].
But, [PCl5]=0.4M,[PCl3]=0.2M,Kc=0.5.
Substitute values in the above expression.
0.5=0.2×[Cl2]0.4]
Thus, [Cl2]=1.0.

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