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Question

In the reaction shown, (X) and (Y) respectively are :
31534_518027956eae4cd6a4ce8da6969a87df.png

A
5-bromosalicylic acid and 5-nitrosalicylic acid
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B
o-bromophenol and o-nitrophenol
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C
2,4,6-tribromophenol and picric acid
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D
3,5-dibromosalicylic acid and 3,5-dinitrosalicylic acid
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Solution

The correct option is C 2,4,6-tribromophenol and picric acid
(X) is 2,4,6-tribromophenol and (Y) is picric acid (2,4,6-trinitrophenol). Bromine and nitric acid both oxidise the carboxylic part and because of highly activated ring (presence of OH group), tribromination and trinitration occurs.

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