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Byju's Answer
Standard XII
Chemistry
Characteristics of Equilibrium Constant
In the revers...
Question
In the reversible reaction
2
H
I
⇌
H
2
+
I
2
,
K
p
is:
A
equal to
K
c
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B
greater than
K
c
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C
0
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D
less than
K
c
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Solution
The correct option is
B
equal to
K
c
Solution:- equal to
K
c
As we know that,
K
p
=
K
c
(
R
T
)
Δ
n
g
2
H
I
(
g
)
⇌
H
2
(
g
)
+
I
2
(
g
)
For the above reaction,
Δ
n
g
=
n
P
−
n
R
=
(
1
+
1
)
−
2
=
0
Therefore,
K
p
=
K
c
(
R
T
)
0
⇒
K
p
=
K
c
Hence for the given reaction,
K
p
is equal to
K
c
.
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Similar questions
Q.
In a reversible reaction
H
2
+
I
2
⇋
2
H
I
, if the concentration of
H
2
and
I
2
are increased, the value of
K
c
:
Q.
For the reaction,
2
N
O
2
(
g
)
⇋
2
N
O
(
g
)
+
O
2
(
g
)
,
(
K
C
=
1.8
×
10
−
6
a
t
184
∘
C
)
(R = 0.0831 kJ/(mol.K))
when
K
p
and
K
c
are compared at
184
∘
C
it is found that
Q.
Assertion :For the reaction
H
2
+
I
2
⇌
2
H
I
,
K
p
=
K
c
. Reason: If
K
p
=
K
C
for a reaction, the sum of stoichiometric coefficient of reactants should be equal to the sum of stoichiometric coefficients of products.
Q.
At
445
∘
C
,
K
c
for the following reaction is 0.020.
2
H
I
(
g
)
⇌
H
2
(
g
)
+
I
2
(
g
)
A mixture of
H
2
,
I
2
, and HI in a vessel at
445
∘
C
has the following concentrations:
[
H
I
]
=
2.0
M
,
[
H
2
]
=
0.50
M
a
n
d
[
I
2
]
=
0.10
M
. Which one of the following statements concerning the reaction quotient,
Q
c
, is TRUE for the above system?
Q.
Assertion :
K
p
can be equal to or less than or even greater than the value of
K
c
. Reason:
K
p
=
K
c
(
R
T
)
Δ
n
the relation between
K
p
and
K
c
depends on the change in the number of moles of gaseous reactants and products.
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