Dear student
NaCl is an ionic crystal. Sodium can donate its outer most electron to the chlorine and form Na+ and Cl- ions. In an ionic solid the cations are surrounded by anions and each anion is surrounded by cations. In case of sodium crystal, each Na+ ion is surrounded by six Cl– ions and vice versa. Each ion thus attains a closed outer shell of electrons and takes on a spherical shape. This is why sodium chloride does not exist as a single quantity.
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